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Open access

ISSN: 2468-0257
CN: 10-1418/TK
p-ISSN: 2096-2797

Sacrificial Cr-Triggered Cascade Reconstruction of NiFe LDH: Balancing Active Site Density and Intrinsic Activity for Water Oxidation

NiFe-based layered double hydroxides (LDHs) are among the most effective oxygen evolution reaction (OER) catalysts, yet their performance is fundamentally constrained by the quantity-quality paradox:...

Constructing NiO/CoMn2O4 heterojunction enables efficient and robust rechargeable zinc air battery

Designing low-cost and high-performance bifunctional electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is a key issue for the development of rechargeable zinc-air...

Chemical-biological synergistic strategies for the valorisation of waste carbon resources

The generation of waste is a significant challenge posed by industrialisation and population growth. The present viewpoint paper explores chemical-biological synergistic strategies for the valorisation...

Disrupting Interfacial Hydrogen-Bond Networks to Build a Local H2O-Poor Microenvironment for Durable Aqueous Zn Anodes

Aqueous zinc metal anodes (ZMAs) suffer from H2O-driven parasitic reactions and dendritic plating, both rooted at the electrode-electrolyte interface. Herein, we report a molecular microenvironment...

Boosting Hybrid Supercapacitor Performance via Synergy between Ti-Doped Ni0.85Se Nanospheres and Ferrocyanide-Enhanced Electrolyte

The trade-off between energy and power density remains a major hurdle for supercapacitors (SCs). This work demonstrates a substantial performance enhancement in aqueous hybrid supercapacitors through...

Oil-Soluble Surfactant Regulated Interfacial Polymerization toward Homogeneous Fluorinated Membranes for Crude Oil Separation

Membrane separations without phase transition offer a compelling route to low-energy crude oil fractionation. For practical implementation, membranes are required to simultaneously achieve high permeance,...

Bead-Like MOF Nanosheet Assemblies for High-Loading Thin Mixed-Matrix Membranes in Molecular Separation

Metal-organic framework (MOF)-based molecular separation membranes have great potential in the recovery of organic solvents by pervaporation. Nevertheless, fabricating high-loading mixed-matrix membranes...

Engineering the Artificial Carbon Cycle via Tandem Strategies and Cross-Scale Integration in Electrocatalytic CO2 Reduction

Consumption of fossil fuels has seriously impacted the carbon cycle, creating an urgent need to develop artificial carbon cycles to mitigate climate change. While electrocatalytic carbon dioxide reduction...

Regulating novel electrochemical reactions through transport processes and confinement effects

Achieving high selectivity remains a central challenge in electrosynthesis, particularly as the field advances toward increasingly complex and value-added chemical transformations. Beyond catalyst design,...

Synergistic Electrocatalysis for Enhanced Nitrate Valorization with Dual Strategies of Alternative Anode Reactions and Cathodic Coupling

Renewable electricity-driven nitrate reduction reaction (NO3RR) offers a sustainable strategy for simultaneously producing valuable chemicals and reducing environmental pollutants. Traditional systems...

Catalyst Design for CO and CO2 Hydrogenation Reactions: From Microenvironment Engineering to Selectivity Control

The catalytic hydrogenation of CO and CO2 is fundamental yet practically important in C1 chemistry, leading to sustainable production of fuels and chemicals. A universal challenge across these transformations...

Hotspot-Catalytic Site Synergy Enables Photothermal Closed-Loop Upcycling of Polycarbonate into High-Performance Flame-Retardant Composites

Engineering plastics are essential to modern industry, yet their recycling remains challenging because conventional processes are energy-intensive and often degrade material value. Polycarbonate (PC),...

Recalcitrance barriers in plant cell walls: From hierarchical organization to targeted depolymerization strategies

The plant cell wall represents the most abundant renewable reservoir of organic carbon on Earth, and its efficient conversion is therefore critical for sustainable development. However, the intrinsic...

A Perspective on Ultra-High Temperature and High-Efficiency Energy Storage Targeting Critical Resources

Ultra-high temperature thermal energy storage (UHT-TES) technology offers an important pathway to address the decarbonization needs of critical resource industries. Herein, we provide a perspective...

Promoting sodium storage performance of bacteria-derived carbon/MoS2-MoSe2 heterostructure enabled by carbon dot

Two-dimensional metal sulfides/selenides with high theoretical capacity and unique layered structure have been extensively studied as anode materials for sodium-ion batteries (SIBs). However, they generally...

Achieving Structural-Functional Synergy in Biomass Hydrogel Electrolytes for Dendrite-Free Flexible Zinc-Ion Batteries

The proliferation of flexible electronics demands energy storage devices that are inherently safe, mechanically compliant, and environmentally sustainable. Quasi-solid-state electrolytes are critical...

MOF-Derived Bi/Bi2O3 Heterostructure on N-Doped Carbon: Synergistic Catalysis for CO2 Electroreduction to Formate

The electrochemical reduction of CO2 to formate represents a promising route for sustainable chemical production and carbon utilization. However, developing catalysts that combine high selectivity,...

Enhanced intrinsic water and sulfur dioxide tolerance of Cu-SSZ-13 for NH3-SCR via surface Al siting and micropore confinement

Low-temperature nitrogen oxides (NOx) abatement is critically hindered by catalyst deactivation in H2O- and SO2-containing atmospheres, severely limiting the practical application of NH3-selective catalytic...

Regulation of the molecular structure of carbon nitride by dual carboxylic group and nitrogen vacancy modulation for photocatalytic carbon dioxide reduction

The photoconversion efficiency of CO2 is hindered by severe charge recombination and sluggish multi-electron kinetics at the surface reaction. For strengthening CO2 adsorption and activation process,...

Fluorine-Induced Local Electronic Restructuring on LiMn2O4 Surface for Enhanced Selective Lithium Extraction

This work targets the long-standing limitations of spinel LiMn2O4 (LMO) in electrochemical lithium extraction from salt-lake brines, including manganese dissolution, surface structural instability,...

Synergistic thermal-mass enrichment on macro-mesoporous N,S-codoped carbon derived from used tea for ultrafast nitroaromatics reduction

Nitroaromatic reduction is one of the most valuable industrial reactions; however, the development of eco-friendly carbon-based metal-free catalysts is extremely limited by their low activities and...

Dense Crystalline–Amorphous Interfaces Modulate Competitive Adsorption for Efficient Biomass Upgrading

The 5-hydroxymethylfurfural oxidation reaction (HMFOR) is a promising approach for biomass upgrading. However, the mechanistic complexity of HMFOR poses limitations on its widespread adoption. In particular,...

Perovskite cathode with self-exsolved CoFe nanoparticles for efficient hydrogen evolution in ammonia solid oxide electrolysis cell

Ammonia electrolysis via solid oxide cell (NH3-SOEC) offers a promising hydrogen production route with low electricity consumption and carbon-free operation. However, compared with conventional solid...

Fe-N Coordination Tunes Lattice Oxygen Mobility in Fe@CN for Selective Oxidation of Crude 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid

Owing to the scarcity of natural resources, the polyester industries have turned to synthesizing 2,5-Furandicarboxylic acid (FDCA) from 5-hydroxymethylfurfural (HMF) to replace terephthalic acid for...

MOF-Assisted Catalytic Laser-Induced Pyramid-Array Graphene on Biomass for Efficient Solar Desalination

Solar-driven interfacial evaporators from biomass provide a sustainable solution for freshwater production, yet their deployment is often constrained by inefficient light harvesting, limited purification...

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